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- W1978760103 abstract "The use of catechols, and more specifically of dopamine, as a specific redox mediator for scanning electrochemical microscopy (SECM) investigations was evaluated in the challenging situation of an ultrathin layer deposited on a conductive substrate (carbon materials). Experiments show that dopamine is a well-adapted redox system for SECM in feedback mode and in unbiased conditions. Used as a redox mediator, catechol permits the investigations of modified surfaces without an electrical connection of the sample thanks to fast charge transfer kinetics but with a surface selectivity that does not exist in classical outer-sphere redox mediators. The interest of catechol in SECM as a sensitive redox mediator is exemplified by monitoring several modification steps of an ultrathin (<1 nm) hierarchically porous organic monolayer deposited on carbon substrates. For quantitative analysis, the SECM approach curves using dopamine could simply be characterized with an irreversible electron transfer kinetics model in a large range of pH." @default.
- W1978760103 created "2016-06-24" @default.
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- W1978760103 date "2012-08-15" @default.
- W1978760103 modified "2023-10-12" @default.
- W1978760103 title "Use of Catechol As Selective Redox Mediator in Scanning Electrochemical Microscopy Investigations" @default.
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- W1978760103 doi "https://doi.org/10.1021/ac301634s" @default.
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