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• W1978761743 abstract "Here we show that essentially any Fe compounds spanning Fe salts, nanoparticles, and buckyferrocene could serve as catalysts for single-walled carbon nanotube (SWNT) forest growth when supported on AlOx and annealed in hydrogen. This observation was explained by subsurface diffusion of Fe atoms into the AlOx support induced by hydrogen annealing where most of the deposited Fe left the surface and the remaining Fe atoms reconfigured into small nanoparticles suitable for SWNT growth. Interestingly, the average diameters of the SWNTs grown from all iron compounds studied were nearly identical (2.8–3.1 nm). We interpret that the offsetting effects of Ostwald ripening and subsurface diffusion resulted in the ability to grow SWNT forests with similar average diameters regardless of the initial Fe catalyst." @default.
• W1978761743 created "2016-06-24" @default.
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• W1978761743 date "2012-01-17" @default.
• W1978761743 modified "2023-10-18" @default.
• W1978761743 title "Role of Subsurface Diffusion and Ostwald Ripening in Catalyst Formation for Single-Walled Carbon Nanotube Forest Growth" @default.
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• W1978761743 doi "https://doi.org/10.1021/ja208706c" @default.
• W1978761743 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22233092" @default.
• W1978761743 hasPublicationYear "2012" @default.
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