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• W1978763904 abstract "Resonant soft X-ray emission spectra have been measured at the Ni 2p edge of a planar nickel complex K2Ni(CN)4·H2O and interpreted by performing ab initio configuration interaction calculations. This cyano complex shows characteristic metal-to-ligand charge transfer (MLCT) bands in the Ni 2p photoabsorption spectra. Resonant soft X-ray emission via the MLCT intermediate states can be interpreted as valence MLCT excitations within a one-electron picture. On the other hand, resonant soft X-ray emission via the intra-atomic Ni 2p–3d intermediate state corresponding to the white line excitation shows significant electron correlation effects." @default.
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• W1978763904 date "2001-03-01" @default.
• W1978763904 modified "2023-10-17" @default.
• W1978763904 title "Valence excitations observed in resonant soft X-ray emission spectra of K2Ni(CN)4·H2O at the Ni 2p edge" @default.
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• W1978763904 doi "https://doi.org/10.1016/s0368-2048(00)00309-1" @default.
• W1978763904 hasPublicationYear "2001" @default.
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