FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1978766075> ?p ?o ?g. }

• W1978766075 endingPage "5757" @default.
• W1978766075 startingPage "5752" @default.
• W1978766075 abstract "Abstract Methods for removing the residual Grubbs' third generation catalyst from polymers prepared by ring opening metathesis polymerization are reported. Two strategies were investigated for reduction of the residual catalyst in the final polymer product. The first strategy involved the use of heterogeneous functionalized particles to scavenge the catalyst from the solution. Filtration of the particles followed by precipitation produced polymers with 10–60 ppm residual catalyst, depending on the type of particle used, surface functional groups, and number of equivalents. The second strategy used small organic molecules that could coordinate to the metal species and modify the solubility of the catalyst, facilitating partitioning of the catalyst into the precipitation solvent. Several types of molecules with varied functionality reduced the residual catalyst level to 30–120 ppm, depending on the loading. Hydrogenation of the polymer backbone followed by precipitation lowered the residual Ru content from 195 ppm to 10 ppm, suggesting that the difficulty of completely removing the catalyst could be a result of coordination of the metal species to the double bonds in the polymer backbone. Reducing the amount of trace catalyst significantly improved the oxidative stability of the polymer. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010" @default.
• W1978766075 created "2016-06-24" @default.
• W1978766075 creator A5016308948 @default.
• W1978766075 creator A5021060619 @default.
• W1978766075 creator A5022848256 @default.
• W1978766075 creator A5079674988 @default.
• W1978766075 date "2010-10-22" @default.
• W1978766075 modified "2023-10-18" @default.
• W1978766075 title "Methods for removal of residual catalyst from polymers prepared by ring opening metathesis polymerization" @default.
• W1978766075 cites W1963809993 @default.
• W1978766075 cites W1965890229 @default.
• W1978766075 cites W1967884250 @default.
• W1978766075 cites W1977321526 @default.
• W1978766075 cites W1978382867 @default.
• W1978766075 cites W1979775657 @default.
• W1978766075 cites W1982810141 @default.
• W1978766075 cites W1982980890 @default.
• W1978766075 cites W1984416928 @default.
• W1978766075 cites W1985108907 @default.
• W1978766075 cites W1989961129 @default.
• W1978766075 cites W1991959367 @default.
• W1978766075 cites W1992896850 @default.
• W1978766075 cites W1994092799 @default.
• W1978766075 cites W2007252698 @default.
• W1978766075 cites W2008771542 @default.
• W1978766075 cites W2010054282 @default.
• W1978766075 cites W2010732799 @default.
• W1978766075 cites W2027955099 @default.
• W1978766075 cites W2030155051 @default.
• W1978766075 cites W2035122819 @default.
• W1978766075 cites W2037528669 @default.
• W1978766075 cites W2042389194 @default.
• W1978766075 cites W2047048604 @default.
• W1978766075 cites W2053689749 @default.
• W1978766075 cites W2063420315 @default.
• W1978766075 cites W2063992911 @default.
• W1978766075 cites W2064419657 @default.
• W1978766075 cites W2066780042 @default.
• W1978766075 cites W2068863726 @default.
• W1978766075 cites W2079798470 @default.
• W1978766075 cites W2083989748 @default.
• W1978766075 cites W2094411497 @default.
• W1978766075 cites W2096337855 @default.
• W1978766075 cites W2098456463 @default.
• W1978766075 cites W2147272137 @default.
• W1978766075 cites W2772224053 @default.
• W1978766075 cites W2949333443 @default.
• W1978766075 cites W4251662638 @default.
• W1978766075 doi "https://doi.org/10.1002/pola.24380" @default.
• W1978766075 hasPublicationYear "2010" @default.
• W1978766075 type Work @default.
• W1978766075 sameAs 1978766075 @default.
• W1978766075 citedByCount "26" @default.
• W1978766075 countsByYear W19787660752012 @default.
• W1978766075 countsByYear W19787660752013 @default.
• W1978766075 countsByYear W19787660752014 @default.
• W1978766075 countsByYear W19787660752015 @default.
• W1978766075 countsByYear W19787660752016 @default.
• W1978766075 countsByYear W19787660752018 @default.
• W1978766075 countsByYear W19787660752019 @default.
• W1978766075 countsByYear W19787660752020 @default.
• W1978766075 countsByYear W19787660752021 @default.
• W1978766075 crossrefType "journal-article" @default.
• W1978766075 hasAuthorship W1978766075A5016308948 @default.
• W1978766075 hasAuthorship W1978766075A5021060619 @default.
• W1978766075 hasAuthorship W1978766075A5022848256 @default.
• W1978766075 hasAuthorship W1978766075A5079674988 @default.
• W1978766075 hasConcept C107054158 @default.
• W1978766075 hasConcept C111998727 @default.
• W1978766075 hasConcept C121332964 @default.
• W1978766075 hasConcept C127413603 @default.
• W1978766075 hasConcept C153294291 @default.
• W1978766075 hasConcept C153914509 @default.
• W1978766075 hasConcept C161790260 @default.
• W1978766075 hasConcept C178394782 @default.
• W1978766075 hasConcept C178790620 @default.
• W1978766075 hasConcept C185592680 @default.
• W1978766075 hasConcept C188027245 @default.
• W1978766075 hasConcept C2780471494 @default.
• W1978766075 hasConcept C42360764 @default.
• W1978766075 hasConcept C44228677 @default.
• W1978766075 hasConcept C521977710 @default.
• W1978766075 hasConcept C90958600 @default.
• W1978766075 hasConceptScore W1978766075C107054158 @default.
• W1978766075 hasConceptScore W1978766075C111998727 @default.
• W1978766075 hasConceptScore W1978766075C121332964 @default.
• W1978766075 hasConceptScore W1978766075C127413603 @default.
• W1978766075 hasConceptScore W1978766075C153294291 @default.
• W1978766075 hasConceptScore W1978766075C153914509 @default.
• W1978766075 hasConceptScore W1978766075C161790260 @default.
• W1978766075 hasConceptScore W1978766075C178394782 @default.
• W1978766075 hasConceptScore W1978766075C178790620 @default.
• W1978766075 hasConceptScore W1978766075C185592680 @default.
• W1978766075 hasConceptScore W1978766075C188027245 @default.
• W1978766075 hasConceptScore W1978766075C2780471494 @default.
• W1978766075 hasConceptScore W1978766075C42360764 @default.
• W1978766075 hasConceptScore W1978766075C44228677 @default.
• W1978766075 hasConceptScore W1978766075C521977710 @default.

• next