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- W1978770539 abstract "The kinetics of the addition reactions of tetracyanoethylene (TCNE) to trans-[Rh(RNC)2(PR′3)2]ClO4, where R = p-CH3OC6H4, p-ClC6H4, and C6H11 and R′ = C6H5 and C6H5O, in acetonitrile, acetone, and tetrahydrofuran (THF) have been investigated employing stopped-flow techniques. The reaction is first order with respect to both complex and TCNE. The reaction rate increases with increasing solvent polarity in the order of THF < acetone < acetonitrile. The activation parameters for the reactions of [RH(p-CH3OC6H4NC)2(PPh3)2]ClO4 in the three solvents were: ΔH*, 7.6, 3.5, 2.2 kcal mol−1; ΔS*, −15.2, −27.7, −28. e.u. The nature of the transition state and ligand effects on the rate of reaction are discussed." @default.
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- W1978770539 date "1975-01-01" @default.
- W1978770539 modified "2023-09-27" @default.
- W1978770539 title "Kinetics of the addition reactions of tetracyanoethylene towards rhodium(I) cationic isocyanide complexes" @default.
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- W1978770539 doi "https://doi.org/10.1016/s0020-1693(00)89841-2" @default.
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