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• W1978788585 abstract "The electronic structure of pyrochlore-type ${mathrm{Tl}}_{2}{mathrm{Ru}}_{2}{mathrm{O}}_{7},$ which undergoes a metal-semiconductor transition at ${T}_{t}ensuremath{sim}120mathrm{K},$ has been studied by ultraviolet photoemission spectroscopy (UPS) and inverse-photoemission spectroscopy [bremsstrahlung isochromat spectroscopy (BIS)]. The temperature dependence of the UPS intensity around the Fermi level ${(E}_{F}),$ which is largely due to the Ru $4d$ states, reflects the transition. In the BIS spectra, changes occur across the metal-semiconductor transition not only near ${E}_{F}$ but also several eV above ${E}_{F}$ where the Ru $4d$ ${e}_{g}$ states and the Tl $6s$ states are dominant. It is therefore concluded that the transport properties across the metal-semiconductor transition in ${mathrm{Tl}}_{2}{mathrm{Ru}}_{2}{mathrm{O}}_{7}$ are mainly determined by the Ru ${4dt}_{2g}$ states around ${E}_{F}$ but that the changes in the Tl $6s$ states also make contributions to the transition." @default.
• W1978788585 created "2016-06-24" @default.
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• W1978788585 date "2004-01-30" @default.
• W1978788585 modified "2023-10-02" @default.
• W1978788585 title "Photoemission study of electronic structure and metal-semiconductor transition in pyrochlore-type<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>Tl</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>Ru</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mrow><mml:mi …" @default.
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• W1978788585 doi "https://doi.org/10.1103/physrevb.69.035115" @default.
• W1978788585 hasPublicationYear "2004" @default.
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