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- W1978796640 abstract "Abstract Diblock copolymers, poly[(10‐hydroxydecanoic acid)‐ block ‐styrene] (PHDA‐ b ‐PSt), were synthesized by combining enzymatic condensation polymerization of HDA and atom transfer radical polymerization (ATRP) as of St PHDA was first obtained via enzymatic condensation polymerization catalyzed by Novozyme‐435. Subsequently, one terminus of the PHDA chains was modified by reaction with α‐bromopropionyl bromide and the other terminus was protected by chlorotrimethylsilane. The resulting monofunctional macroinitiator was used subsequently in ATRP of St using CuCl/2,2′‐bipyridine as the catalyst system to afford diblock copolymers including biodegradable PHDA blocks and well‐defined PSt blocks. Polymeric nanospheres were prepared by self‐assembly of the PHDA‐ b ‐PSt diblock copolymers in aqueous medium. Copyright © 2008 Society of Chemical Industry" @default.
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- W1978796640 date "2008-01-08" @default.
- W1978796640 modified "2023-09-30" @default.
- W1978796640 title "Synthesis of poly[(decanoic acid)-block-styrene] diblock copolymers and their self-assembly behavior in aqueous medium" @default.
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- W1978796640 doi "https://doi.org/10.1002/pi.2120" @default.
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