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- W1978798255 abstract "Abstract The adsorption of α-, ⨿- and γ-cyclodextrins on mercury electrodes from l M NaClO 4 and 0.5 M Na 2 SO 4 was investigated, using surface tension and differential capacity measurements. All three cyclodextrins adsorb on mercury and, in addition, α- and γ-cyclodextrins exhibit a behaviour typical of the two-dimensional condensation of organic adsorbates in both electrolytes. They also show strong reorientation effects in the adsorbed state. A comparison of possible models of electrode occupation by surfactant molecules with the experimentally determined surface excesses shows that at less negative potentials the molecules of cyclodextrins are oriented with the cavity perpendicular to the electrode surface, while at more negative potentials an orientation intermediate between the “parallel” and “perpendicular” prevails." @default.
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- W1978798255 date "1988-10-01" @default.
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- W1978798255 title "Adsorption of α-, ⨿- and γ-cyclodextrins on mercury electrodes from 1 M NaC1O4 and 0.5 M Na2SO4 aqueous solutions" @default.
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- W1978798255 doi "https://doi.org/10.1016/0022-0728(88)80227-4" @default.
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