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- W1978799765 abstract "The structural and electronic properties of the series Bi2−xFe1+xSbO7 (0 ⩽ x ⩽ 0.6) were investigated using a combination of diffraction and spectroscopy. Synchrotron and neutron diffraction analysis show that Fe3+ cations substitute for Bi3+ onto the A site with increasing x, which was further confirmed by analysis of the Fe K/L-edge X-ray absorption near-edge spectra. The diffraction analysis indicated the presence of displacive disorder along the A2O chains, likely the result of the Bi3+ 6s2 lone pair, as well as non-Vegard-like behaviour of the lattice parameters in the Fe-poor region. Fe K-edge extended X-ray absorption fine-structure analysis of Bi2FeSbO7 confirmed the displacive disorder of the Bi3+ cations as well as Sb5+ and Fe3+ disorder on the B site." @default.
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- W1978799765 date "2014-03-01" @default.
- W1978799765 modified "2023-10-17" @default.
- W1978799765 title "Diffraction and spectroscopic study of pyrochlores Bi2−xFe1+xSbO7" @default.
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- W1978799765 doi "https://doi.org/10.1016/j.jallcom.2013.11.226" @default.
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