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• W1978803707 abstract "Using a modification of a recently reported convenient synthesis of the isobutyl ester form of the bis(isothiocyanato) ruthenium dye (N3), we report the isolation and spectroscopic characterization of the minor isomer in which one NCS− is N-bound and the other is S-bound. The synthesis involves the reaction of Ru(iBu2dcbpy)2Cl2, where iBu2dcbpy is the diisobutyl ester of 4,4′-dicarboxy-2,2′-bipyridine, with a source of thiocyanate. The impact of the isocyanate salt, solvent, and temperature on the yield of the linkage isomers is presented. In addition to the two linkage isomers 1 and 2, the partially substituted chloroisothiocyanato complex 3, Ru(iBu2dcbpy)2Cl(NCS), was also isolated. Selective removal of the chloride using silver triflate provided a path to [Ru(iBu2dcbpy)2(pyridine)(NCS)]OTf, 4, in high yield. The complexes were characterized by 1H and 13C NMR, IR, and electronic absorption spectroscopies and mass spectrometry. At 80 °C in DMSO-d6, the isomerization of 2 to 1 is complete and exhibits fir..." @default.
• W1978803707 created "2016-06-24" @default.
• W1978803707 creator A5007807148 @default.
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• W1978803707 date "2014-01-02" @default.
• W1978803707 modified "2023-09-26" @default.
• W1978803707 title "Thiocyanate linkage isomerism in the isobutyl ester form of the ruthenium dye known as N3" @default.
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• W1978803707 doi "https://doi.org/10.1080/00958972.2013.879984" @default.
• W1978803707 hasPublicationYear "2014" @default.
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