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- W1978826543 abstract "The reaction of the cluster salt K4[Re4Te4(CN)12]·5H2O with NdCl3·6H2O was studied in either an acidic medium (HCl) or in a water solution in the presence of the following organic agents: hexafluoroacetylacetonate, 2,2′-bipyridine or 1,10-phenanthroline (phen). The crystal structures of four new compounds have been solved by single crystal X-ray diffraction analysis: (H)[{Nd(H2O)5}{Re4Te4(CN)12}]·5.5H2O (1) (space group P21/c, framework structure), K2[{Nd(H2O)7}2{Re4Te4(CN)12}2]·8H2O (2) (space group С2/c, isolated structure), K0.5H0.5[{Nd(H2O)5}{Re4Te4(CN)12}]·3H2O (3) (space group Сmcm, layered structure) and (phenH)[{Nd(H2O)2(phen)2}{Re4Te4(CN)12}]·11H2O (4) (space group С2/c, chain structure). 1,10-Phenanthroline was found to have been incorporated into the structure of compound 4, whilst hexafluoroacetylacetonate and 2,2′-bipyridine did not enter the structures of 2 and 3. It was shown that the structures of compounds 2–4 differ dramatically from that found for compound 1, which was obtained in the absence of the organic agents." @default.
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- W1978826543 date "2012-01-01" @default.
- W1978826543 modified "2023-10-18" @default.
- W1978826543 title "The influence of organic agents on the resultant crystal structure in the reactions of the [Re4Te4(CN)12]4− tetrahedral cluster anion with Nd3+ cations" @default.
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- W1978826543 doi "https://doi.org/10.1016/j.poly.2011.10.020" @default.
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