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- W1978853221 abstract "The ground state in-plane normal coordinates of glyoxal-h2, -d2 and -hd are calculated in the valence force field approximation. The experimental data, taken from the literature, are the complete set of ground state in-plane fundamental frequencies and the geometrical structure determined by combining electron diffraction and spectroscopic data. A quite complete and reasonable force field is obtained corresponding to a good agreement between observed and calculated frequencies (standard deviation 5.3 cm−1). The potential energy distributions and the Cartesian displacements were calculated and are given for each mode. A possible application to Franck—Condon factor calculations is discussed in particular with respect to the observed modification of the relative activity of modes 3 and 4 in the electronic spectra of the three isotopic species considered." @default.
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- W1978853221 date "1978-01-01" @default.
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- W1978853221 title "The in-plane normal modes of vibration of glyoxal-h2, -d2 and -hd" @default.
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- W1978853221 doi "https://doi.org/10.1016/0584-8539(78)80169-x" @default.
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