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- W1978862880 abstract "CSH(SO 4 ) 0.76 (SeO 4 ) 0.24 , M m = 241.2, single crystals were grown and appear to be isomorphous with CsHSeO 4 . The space group is P2 1 /a, the lattice constants are: a = 7.8340(10) A, b = 8.2147(6) A, c = 7.4440(10) A, β = 110.910(10)°, V = 447.50(9) A 3 , Z = 4, D x = 3.582 Mg m -3 , λ (MoK α ) = 0.71069 A, μ(MoK α ) = 10.269 mm -1 . F(000) = 818, T = 293(2) K (room temperature phase), R = 0.023 and wR = 0.0563 for 883 observed reflections. The hydrogen sulphate or hydrogen selenate groups are connected by hydrogen bonds. The separated chains of asymmetric hydrogen bonds run parallel to the c-axis. The O-H...O distance utilized in the hydrogen bonding is 2.608 A which is 2.603 A for CsHSeO 4 . Mixed cesium hydrogen sulphate selenate CsH(SO 4 ) 0.76 (SeO 4 ) 0.24 undergoes two phase transitions at T = 333 and 408 K. The values of the enthalpies are 2.02 and 4.37 kJ/mol, respectively." @default.
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- W1978862880 date "1997-03-01" @default.
- W1978862880 modified "2023-09-23" @default.
- W1978862880 title "Structural Phase Transitions and Vibrational Study of CsH(SO4)0.76(SeO4)0.24" @default.
- W1978862880 doi "https://doi.org/10.1002/1521-3951(199703)200:1<3::aid-pssb3>3.0.co;2-z" @default.
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