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- W1978890738 abstract "[Co3(CO)9(μ3-CX)] (X H, Cl) react with S2CPR3 (R cyclohexyl, Cy or isopropyl, iPr) in CH2 Cl2 to give heptacarbonyltricobalt clusters [CO3(CO)7(μ3-CX)(μ2-S2CPR3)] in which the S2CPR3 act as four-electron ligands, bridging a CoCo cluster edge in a σ(S), σ(S′) fashion, as shown by an X-ray determination on a crystal of the derivative with X H, R Cy. The five-membered CoSCSCo ring is nearly perpendicular to the CO3 triangle (i.e. axial), in contrast to the equatorial disposition usually found in related complexes with phosphorus ligands." @default.
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- W1978890738 date "1992-06-01" @default.
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- W1978890738 title "S2CPR3 adducts as bridging ligands in tricobalt clusters. X-Ray structure of [Co3(CO)7(μ3-CH)(μ-S2CPCy3)]" @default.
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- W1978890738 doi "https://doi.org/10.1016/0022-328x(92)80108-a" @default.
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