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- W1978918431 abstract "A series of iron(III)-containing imidazolium salts of the general formula [DRim][FeX4] (R = 2,6-diisopropylphenyl, IPr, X = Cl, 1; R = IPr, X = Br, 2; R = tertbutyl, t Bu, X = Cl, 3; R = isopropyl, i Pr, X = Cl, 4; R = benzyl, Bn, X = Cl, 5; R = Bn, X = Br, 6) have been prepared in high yields via reactions of anhydrous ferric halides with equivalent of the corresponding N,N-dihydrocarby-limidazolium halides, where 2–6 are novel ones. All of the complexes were characterized by elemental analysis, Raman spectroscopy, electrospray ionization mass spectroscopy, and X-ray crystallography for 1 and 2. All of them were non-hygroscopic and air-stable, with four of them existing as solids (1–4) and two as liquids (5 and 6) at room temperature. A preliminary catalytic study on the coupling of 4-tolylmagnesium bromide with cyclohexyl bromide revealed that 1 and 3 possessed the highest activity. In comparison, 2, 4 and 5 exhibited moderate activity and the least active complex was 6." @default.
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- W1978918431 date "2012-10-23" @default.
- W1978918431 modified "2023-10-16" @default.
- W1978918431 title "Synthesis, structure of iron(III)-containing imidazolium salts and their catalytic activity in the alkylation of aryl Grignard reagents" @default.
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- W1978918431 doi "https://doi.org/10.1007/s11434-012-5513-4" @default.
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