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- W1978925939 endingPage "015001" @default.
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- W1978925939 abstract "Gelation of tannin–formaldehyde (TF) solutions was systematically investigated by changing pH and concentration of TF resin in water. In this way we constructed the TF phase diagram, from which chemical hydrogels could be described, and also synthesized thermoreversible tannin-based hydrogels. Conditions of non-gelation were also determined. Hydrogels were dried in supercritical CO2, leading to a broad range of TF aerogels. The latter were investigated for volume shrinkage, total porosity, micro-, meso- and macropore volumes, Brunauer–Emmett–Teller (BET) surface area, microscopic texture, mechanical and thermal properties. All these properties are discussed in relation to each other, leading to an accurate and self-consistent description of these bioresource-based highly porous materials. The conditions for obtaining the highest BET surface area or mesopore volume were determined and explained in relation to the preparation conditions. The highest BET surface area, 880 m2 g−1, is remarkably high for organic aerogels derived from a natural resource." @default.
- W1978925939 created "2016-06-24" @default.
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- W1978925939 date "2013-02-01" @default.
- W1978925939 modified "2023-10-06" @default.
- W1978925939 title "Systematic studies of tannin–formaldehyde aerogels: preparation and properties" @default.
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- W1978925939 doi "https://doi.org/10.1088/1468-6996/14/1/015001" @default.
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