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- W1978936174 abstract "A short, efficient, and diastereomerically pure synthesis of N-Boc-cis-4-trifluoromethyl-L-proline (7) and N-Boc-cis-4-difluoromethyl-L-proline (9) from N-Boc-4-oxo-L-proline (4) is described. The reaction of 4 with Me(3)SiCF(3) and the conversion of the carbonyl group of 4 into the difluoromethylene group are the key steps for the synthesis of 7 and 9, respectively." @default.
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- W1978936174 date "2002-09-11" @default.
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- W1978936174 title "Practical Synthesis of Boc-Protected <i>cis</i>-4-Trifluoromethyl and <i>cis</i>-4-Difluoromethyl-<scp>l</scp>- prolines" @default.
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- W1978936174 doi "https://doi.org/10.1021/jo0257400" @default.
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