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- W1978973925 abstract "The influence of the ionic dissociation equilibrium on the photochemical and photophysical properties of xanthene dye onium salts (XTOn) was studied. The dissociation constants (KD) determined by conductivity verify that the ionic association states directly influence the changes in the absorption spectral shape, and the ratio I532/I445 reflects the degree of dissociation of the system. The results of static v fluorescence quenching and dynamic lifetime quenching experiments demonstrate that the electron transfer of XTOn is mainly intra-ion pair electron transfer; the quenching rate constants of intra-ion pair electron transfer approach 1012–1013 s−1 M−1, which is well above the rate limit controlled by diffusion. The effects of substituents and solvents show that the process of electron transfer is controlled by the degree of association, and the efficiency of photosensitized initiation may be improved further by a shift in the equilibrium." @default.
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- W1978973925 date "1996-05-01" @default.
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- W1978973925 title "Photoinduced electron transfer in the ion pair compound (XTOn): influence of ionic association" @default.
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- W1978973925 doi "https://doi.org/10.1016/1010-6030(95)04265-2" @default.
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