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- W1978974422 abstract "Polarographic reduction of 1-thiocarbamoyl-3,5-dimethyl-4-substituted arylazopyrazoles and 1-thiocarbamoyl-3,5-diphenyl-4-substituted arylazopyrazoles gives well-defined, irreversible, diffusion-controlled cathodic waves corresponding to two electron transfer. The studies for the former were made in Britton-Robinson buffers of pH range 3.0 to 10.0, while for the latter the studies were carried out in dimethylformamide. The value of E1/2 shifts with increasing concentration of pyrazoles reveals irreversible reduction. Effect of electron donating substituents on E1/2 for both the series of compounds is reported. It was observed that the same group viz.−OCH3 and −OC2H5 shifts E1/2 towards more, positive value at the ortho position, while E1/2 is shifted towards more negative value at the para position." @default.
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- W1978974422 date "1974-08-01" @default.
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- W1978974422 title "Polarographic reduction of some potential antineoplastic compounds" @default.
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- W1978974422 doi "https://doi.org/10.1016/s0022-0728(74)80415-8" @default.
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