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- W1978974747 abstract "The mononuclear [Mn(6'Me(2)indH)(H(2)O)(2)(CH(3)CN)](ClO(4))(2) (6'Me(2)indH: 1,3-bis(6'-methyl-2'-pyridylimino)isoindoline) complex has been prepared and characterized by various techniques such as elemental analysis, IR, UV-visible and ESR spectroscopy. The title compound was suitable as catalyst for the catalytic oxidation of 3,5-di-tert-butylcatechol (3,5-DTBCH(2)) to 3,5-di-tert-butyl-1,2-benzoquinone (3,5-DTBQ) (catecholase activity), and o-aminophenol (OAPH) to 2-aminophenoxazine-3-one (APX) (phenoxazinone synthase activity) with dioxygen at ambient condition in good yields. Kinetic measurements revealed first-order dependence on the catalyst and dioxygen concentration and saturation type behavior with respect to the corresponding substrate. It was also found that the added triethylamine in both systems accelerates the reaction." @default.
- W1978974747 created "2016-06-24" @default.
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- W1978974747 date "2008-04-01" @default.
- W1978974747 modified "2023-10-10" @default.
- W1978974747 title "Catechol oxidase and phenoxazinone synthase activity of a manganese(II) isoindoline complex" @default.
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- W1978974747 doi "https://doi.org/10.1016/j.jinorgbio.2007.11.014" @default.
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