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- W1978985007 abstract "Various chromiumVI-catalyzed conditions have been tested to improve the oxidation of Δ5-steroids with t-BuOOH to their corresponding 5-en-7-ones. The use of PDC or the association of CrO3 with an amine as the catalyst and CH2Cl2 or PhCF3 as the solvent led usually to the best yields. A minor reaction pathway was the epoxidation of the double bond." @default.
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- W1978985007 date "2006-05-01" @default.
- W1978985007 modified "2023-10-15" @default.
- W1978985007 title "Improved chromium-catalyzed allylic oxidation of Δ5-steroids with t-butyl hydroperoxide" @default.
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- W1978985007 doi "https://doi.org/10.1016/j.molcata.2006.01.031" @default.
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