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- W1978987844 abstract "This work describes the CH- - -O interactions of acetic acid/D2O and formic acid/D2O mixtures measured as a function of pressure and concentration. The CH stretching frequency of acetic acid shows low sensitivity to dilution with D2O, while the CH vibration absorption was altered into one prominent band at ∼2955 cm−1 as its aqueous solution was compressed. The experimental results are in accord with ab initio calculation predicting a CH stretching band located at ∼2928 cm−1 originated from CH- - -O hydrogen bonding. The pressure was found to strengthen the CH- - -O interactions, while the hydration state in aqueous acetic acid transforms from van-der-Waals-like type to hydrophobic hydration upon pressure applied. Pressure-dependent studies on aqueous formic acid reveal a blueshift in CH stretching frequency analogous to aqueous acetic acid upon the formation of CH- - -O hydrogen bonding. The present study demonstrates that the pressure provides a key to investigate hydrophobic hydration originated from pressure-enhanced CH- - -O interactions." @default.
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- W1978987844 date "2002-07-01" @default.
- W1978987844 modified "2023-09-25" @default.
- W1978987844 title "Hydrophobic hydration in aqueous acetic acid and formic acid solutions probed by high pressure" @default.
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- W1978987844 doi "https://doi.org/10.1016/s0022-2313(02)00267-3" @default.
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