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- W1978996243 abstract "We present a study of angle-resolved photoelectron spectra from oriented, linear NiCO. We address the question: How well do simple cluster models such as oriented NiCO simulate adsorbate molecules with respect to photoemission? The photoemission cross sections are obtained using Hartree-Fock electronic continuum orbitals. For the bonding 5ensuremath{sigma}ifmmode tilde{}else ~{}fi{} orbital, we find oriented NiCO to be a better model than oriented CO. The large magnitude of the 5ensuremath{sigma}ifmmode tilde{}else ~{}fi{} photoionization cross sections relative to the 4ensuremath{sigma}ifmmode tilde{}else ~{}fi{} cross section cannot, however, be explained by our calculations without consideration of backscattering of the photoelectrons ejected ``downward'' into the detector." @default.
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- W1978996243 date "1988-02-15" @default.
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- W1978996243 title "Studies of angle-resolved photoelectron spectra from oriented NiCO: A model for adsorbed CO" @default.
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- W1978996243 doi "https://doi.org/10.1103/physrevb.37.2812" @default.
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