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- W1979039097 abstract "Premixed flames of trimethylaluminum vapors with oxygen have been stabilized at reduced pressures (1 to 4 mm Hg) on a flat-flame burner. The flames show multiple reaction zones. These are investigated spectrophotometrically by taking axial spectral radiance profiles for the characteristic radiation of Al, OH, CH, AlO and for the underlying continuous radiation. The first zone emits mainly the aluminum lines, the AlO and OH bands, and a continuum peaking at 4650 . This continuum is interpreted as being due to the combination reaction of AlO with atomic oxygen. The second zone emits the characteristic spectrum of hydrocarbon flames (CH, C 2 , and OH). The reactions in the first zone appear to be the pyrolytic decomposition of the metal alkyl with liberation of free metal and the subsequent fast reaction of the metal with molecular oxygen. The mechanisms of excitation of AlO and OH are discussed. The reactions in the second zone are the delayed combustion of the hydrocarbon fragments liberated during the pyrolysis." @default.
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- W1979039097 date "1967-01-01" @default.
- W1979039097 modified "2023-09-25" @default.
- W1979039097 title "Spectrophotometric study of premixed trimethylaluminum-oxygen flames" @default.
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- W1979039097 doi "https://doi.org/10.1016/s0082-0784(67)80219-4" @default.
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