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- W1979057907 abstract "Four polypyridyl bridging ligands BL1−4 containing open-chain crown ether, where BL1−3 formed by the condensation of 4,5-diazafluoren-9-oxime with diethylene glycol di-p-tosylate, triethylene glycol di-p-tosylate, and tetraethylene glycol di-p-tosylate, respectively. BL4 formed by the reaction of 4-(1,10-phenanthrolin-5-ylimino)methylphenol with triethylene glycol di-p-tosylate, have been synthesized. Reaction of Ru(bpy)2Cl2·2H2O with BL, respectively, afforded four bimetallic complexes [(bpy)2RuBL1−4Ru(bpy)2]4+ as [PF6]− salts. Electrochemistry of these complexes is consistent with one RuII-based oxidation and several ligand-based reductions. These complexes show metal-to-ligand charge transfer absorption at 439-452 nm and emission at 570-597 nm." @default.
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- W1979057907 date "2008-08-01" @default.
- W1979057907 modified "2023-09-25" @default.
- W1979057907 title "Synthesis, Photophysical, and Electrochemical Properties of Ruthenium(II) Polypyridyl Complexes containing Open-Chain Crown Ether" @default.
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- W1979057907 doi "https://doi.org/10.1002/zaac.200800129" @default.
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