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- W1979065836 abstract "The present study shows that the anion of 2-naphthylacetonitrile is substituted selectively at its Cα by aromatic halides, through a radical nucleophilic substitution mechanism, to give the corresponding α,α-diaryl nitriles in good yields. The regioselectivity of this ambident nucleophile changes with the steric hindrance at the radical centre from the aromatic substrate. The selectivity observed was investigated through a computational model of the key reaction step." @default.
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- W1979065836 date "2012-01-01" @default.
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- W1979065836 title "Synthesis of α,α-diaryl nitriles by radical nucleophilic substitution" @default.
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- W1979065836 doi "https://doi.org/10.1039/c1nj20699k" @default.
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