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- W1979103650 abstract "Binding constants (ks) for a series of phenols to aerosol (Ot (sodium bis(2-ethylhexyl)sulfosuccinat) inverted micelles in 2,2,4-trimethylpentane vary from 87.0 m2exclamation for O-tert-butylphenol to 7510 M/sup -1/ for p-nitrophenol. The other phenols (xC/sub 6/H/sub 4/OH) studied were P-T-Bu, O- and P-CH/sub 3/, P-CH/sub 3/O, P-Cl, and H. The strength of binding is determined by the phenol's hydrogen-bonding ability and its solubility in 2,2,4-trimethylpentane (or equivalently, by its hydrogen-water partition coefficient). The binding of phenol to aerosol Ot water-in-oil microemulsion aggegates in 2,2,4-trimethylpentane shows a decrease in k followed by a plateau value as the water-to-aerosol Ot ratio is increased. This effect is discussed in terms of phenol - water competition for interfacial binding sites. 55 references." @default.
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- W1979103650 date "1981-05-01" @default.
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- W1979103650 title "Binding of phenols to inverted micelles and microemulsion aggregates" @default.
- W1979103650 doi "https://doi.org/10.1021/j150610a031" @default.
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