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- W1979105746 abstract "The solid-state structures of a series of seven substituted 3-methylidene-1H-indol-2(3H)-one derivatives have been determined by single-crystal X-ray diffraction and are compared in detail. Six of the structures {(3Z)-3-(1H-pyrrol-2-ylmethylidene)-1H-indol-2(3H)-one, C13H10N2O, (2a); (3Z)-3-(2-thienylmethylidene)-1H-indol-2(3H)-one, C13H9NOS, (2b); (3E)-3-(2-furylmethylidene)-1H-indol-2(3H)-one monohydrate, C13H9NO2·H2O, (3a); 3-(1-methylethylidene)-1H-indol-2(3H)-one, C11H11NO, (4a); 3-cyclohexylidene-1H-indol-2(3H)-one, C14H15NO, (4c); and spiro[1,3-dioxane-2,3′-indolin]-2′-one, C11H11NO3, (5)} display, as expected, intermolecular hydrogen bonding (N—H⋯O=C) between the 1H-indol-2(3H)-one units. However, methyl 3-(1-methylethylidene)-2-oxo-2,3-dihydro-1H-indole-1-carboxylate, C13H13NO3, (4b), a carbamate analogue of (4a) lacking an N—H bond, displays no intermolecular hydrogen bonding. The structure of (4a) contains three molecules in the asymmetric unit, while (4b) and (4c) both contain two independent molecules." @default.
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- W1979105746 date "2010-01-15" @default.
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- W1979105746 title "Seven 3-methylidene-1<i>H</i>-indol-2(3<i>H</i>)-ones related to the multiple-receptor tyrosine kinase inhibitor sunitinib" @default.
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- W1979105746 doi "https://doi.org/10.1107/s0108270109054134" @default.
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