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- W1979117332 abstract "Abstract The standard enthalpies of formation of intermetallic compounds of some lanthanide–iron systems have been measured by high temperature direct synthesis calorimetry at 1373 ± 2 K. The following results in kJ/mole of atoms are reported: Ce 2 Fe 17 (−1.6 ± 2.8); Pr 2 Fe 17 (−0.2 ± 3.0); Nd 2 Fe 17 (−3.0 ± 2.7); Sm 2 Fe 17 (−3.1 ± 3.2); GdFe 2 (−2.4 ± 3.0); HoFe 2 (−2.6 ± 3.3); ErFe 2 (−1.9 ± 3.0); TmFe 2 (−2.2 ± 2.8); LuFe 2 (−3.6 ± 3.1). The standard enthalpies of formation of some binary and ternary shape memory alloys, which have established technological application, have also been measured. These are: Terfenol-D (−1.5 ± 3.1), Samfenol (−13.6 ± 3.1), Galfenol (−10.4 ± 2.8); Nd 2 Fe 14 B (−9.6 ± 3.2). The values are compared with predicted values of the semiempirical model of Miedema and Coworkers and with predictions by ab initio calculations. We will present a systematic picture of how the enthalpies of formation may be related to the atomic number of the lanthanide element (LA). We will also compare the thermochemical behavior of LA–Ni and the LA–Fe alloys." @default.
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- W1979117332 date "2013-03-01" @default.
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- W1979117332 title "The standard enthalpies of formation of some binary intermetallic compounds of lanthanide–iron systems by high temperature direct synthesis calorimetry" @default.
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- W1979117332 doi "https://doi.org/10.1016/j.jallcom.2012.11.035" @default.
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