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• W1979136382 abstract "The VUV absorption spectrum of N2D4 has been measured in the spectral region 1050–2100 Å using synchrotron radiation. The spectrum, which is largely unstructured, gradually rises from a threshold of 2630 Å and is dominated by three broad peaks of increasing magnitude at ≈ 1940, 1685 and 1400 Å followed by a drop in the absorption at ≈ 1340 Å and then a monotonic rise to the low-wavelength experimental cutoff at 1050 Å. The spectrum can be interpreted either in terms of Rydberg excitations of the nonbonding nitrogen electrons with the broad features resulting from spectral congestion or alternatively, the broad nature of the spectrum may be due to absorption of molecular valence states involvingσ∗←n and σ∗←σ transitions. Mulliken proposed the existence of such valence transitions by analogy with corresponding feature in the isoelectric diatomic halogen molecules." @default.
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• W1979136382 date "1992-01-01" @default.
• W1979136382 modified "2023-10-15" @default.
• W1979136382 title "The VUV spectroscopy of deuterated hydrazine, N2D4" @default.
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• W1979136382 doi "https://doi.org/10.1016/0009-2614(92)80837-2" @default.
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