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• W1979144857 abstract "Two new molecular solids, [1-(2′-Cl-4′-Rbenzyl)pyridinium][bis(maleonitriledithiolato)nickel] [abbreviated as ([ClRBzPy][Ni(mnt)2]), R = Br(1), I(2)], have been prepared and characterized. The Ni(III) ions form a 1-D zigzag alternating chain within a column through Ni ··· S, S … S, or π … π stacking interactions in 1 and a tetramer in 2. The variable temperature magnetic susceptibilities of 1 and 2 in the temperature range 1.8–300 K have been interpreted in terms of a simple dimer model approximation (H = −2JSASB ), revealing strong antiferromagnetic interactions with the fitting value g = 1.98 and J = −231.5 cm−1 for 1, g = 1.96 and J = −245.3 cm−1 for 2." @default.
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• W1979144857 date "2009-03-25" @default.
• W1979144857 modified "2023-09-24" @default.
• W1979144857 title "Syntheses, crystal structures, magnetic properties and theoretical analysis of two new molecular solids based on Ni(mnt)− 2" @default.
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• W1979144857 doi "https://doi.org/10.1080/00958970802617585" @default.
• W1979144857 hasPublicationYear "2009" @default.
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