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- W1979152583 abstract "The influence of mobile phase composition on lipophilicities determined by reversed-phase thin-layer chromatography has been investigated by measurement of RM values of homologous n-alkyl phenyl ketones (methyl- to n-heptyl-,n-decyl- and n-undecylketone) using liquid paraffin as the stationary phase and aqueous mixtures of acetone, methanol and N,N-dimethylformamide as the eluents. Of these, acetone appeared to be the least suitable because at high concentrations it appeared to induce perturbations of the stationary phase. All RM values were made up of contributions from methylene groups, which were found to be almost independent of the type of organic co-solvent, and from the acetophenone moiety, which was strongly affected by the properties of the co-solvent. Extrapolation of the values for methylene groups to pure water showed a tendency for somewhat lower values than predicted from values in alkane—water mixtures." @default.
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- W1979152583 date "1983-01-01" @default.
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- W1979152583 title "Influence of eluent composition on lipophilicity measurements using reversed-phase thin-layer chromatography" @default.
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- W1979152583 doi "https://doi.org/10.1016/s0021-9673(01)96353-8" @default.
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