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- W1979156911 abstract "Reaction of tetracyanoethylene with 6,6-disubstituted derivatives of 3-methylenecyclohexa-1,4-diene gives rise to four classes of adduct: spiro[3,5]nona-5,8-dienes, bicyclo[4,3,0]nona-1,4-dienes, bicyclo[4,3,0]nona-1,3-dienes, and tetracyanopropylbenzene derivatives. The relative proportions of these depend both on the detailed structure of the triene and on the solvent. Both these results and the stereochemistry of the bicyclononadiene adducts are discussed in terms of an ionic mechanism in which the lifetime of the initially formed zwitterion is important. The structures of products from tetracyanoethylene and 2-methylenebicyclo[3,1,0]hex-3-ene derivatives are also consistent with an ionic addition mechanism." @default.
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- W1979156911 date "1972-01-01" @default.
- W1979156911 modified "2023-09-23" @default.
- W1979156911 title "Rearrangements in the cycloaddition of tetracyanoethylene to 3-methylenecyclohexa-1,4-dienes and homofulvenes" @default.
- W1979156911 doi "https://doi.org/10.1039/p19720002971" @default.
- W1979156911 hasPublicationYear "1972" @default.
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