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- W1979164433 abstract "The structural characterizations of the potassium complexes of a pair of dianionic bis(phenolate) ligands, {LR = [−OC6H2(2,4-But)(6-CH2)]2NCH2CH2R} R = NMe2, OMe, crystallized from 1,2,-dimethoxyethane (DME) are recorded, showing them to take the binuclear form [K2LR(DME)3]. A pair of neutral binuclear heterobimetallic isotypic complexes are defined with ytterbium(III), with phenol, as sodium salts, of the form [Yb(LR)(OPh)2Na(DME)(HOPh)], and a further array with samarium(III), of the (partially protonated) form [Sm(LOMe)2Na(OH2)]. A further complex, [Na(DME)3][Yb(*Lpy)2], results from an unusual ligand reduction by an ytterbium(II) species to give a new dianionic Schiff base ligand which is coordinated to ytterbium(III) {*Lpy = −OC6H2(2,4-But)(6-CH=N-CH-2-C6H4N)}." @default.
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- W1979164433 date "2008-02-01" @default.
- W1979164433 modified "2023-10-12" @default.
- W1979164433 title "Synthesis and Structural Characterization of Some Potassium Complexes of Some Bis(phenolate) Ligands and Some Novel Heterobimetallic Binuclear Arrays Formed with Trivalent Lanthanoid Ions" @default.
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- W1979164433 doi "https://doi.org/10.1002/zaac.200700442" @default.
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