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- W1979181640 abstract "The biosynthesis of vitamin B12 has fascinated generations of scientists, but part of the pathway was unknown. The missing enzymatic link has now been found, only to raise more mechanistic questions. Vitamin B12 (cobalamin) is one of the largest known non-polymeric natural products, and it is the only vitamin that is synthesized exclusively by microorganisms. Despite years of study, the biosynthesis of one part of the vitamin is poorly understood. Now the last unknown step in its biosynthesis is revealed. The X-ray crystal structure of BluB, an enzyme that uses molecular oxygen to cleave a flavin mononucleotide cofactor to form the lower ligand of vitamin B12, has been determined. This reaction is an example of an unusual process, the enzymatic destruction of one cofactor to synthesize another." @default.
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- W1979181640 date "2007-03-01" @default.
- W1979181640 modified "2023-10-14" @default.
- W1979181640 title "Molecular cannibalism" @default.
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- W1979181640 doi "https://doi.org/10.1038/446387a" @default.
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