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- W1979190337 abstract "The aminolysis of N-acyllactams with n-butylamine was carried out in N,N-dimethylformamide at 25°C. The amine reacted with both of exo- and endocyclic carbonyl groups in the N-benzoyl derivatives of bicyclic oxalactams, such as 8-oxa-6-azabicyclo[3.2.1]octan-7-one (1) and the 4(e)-bromo-substituted analogue. In contrast, only the exocyclic carbonyl group in the monocyclic N-benzoyllactams, N-benzoyl-2-pyrrolidone and N-benzoyl-ε-caprolactam, reacted under the same conditions. These results reflect high reactivity of the bicyclic oxalactams in the base-catalyzed ring-opening polymerization. The present aminolysis was kinetically analyzed in order to estimate the reactivity of N-acyllactams more quantitatively." @default.
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- W1979190337 date "1988-08-01" @default.
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- W1979190337 title "Aminolysis of N-Acyl Derivatives of Bicyclic Oxalactams" @default.
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- W1979190337 doi "https://doi.org/10.1295/polymj.20.615" @default.
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