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- W1979192016 abstract "The ability of the (100) face of tungsten to catalyze ethane hydrogenolysis has been investigated. At 573 K, methane is formed with a specific activity of 0.01 molecules per surface tungsten atom per second (100 Torr H2, 1 Torr C2H6), with no evidence of catalyst deactivation even after several hundred turnovers. Hydrogenolysis is approximately first-order in ethane and half-order in dihydrogen, and displays an apparent activation energy of 27 kcal/mol. Negligible activity is displayed by clean tungsten; the true catalyst appears to be a monolayer of carbide which is formed on the surface of the tungsten on exposure to the reactants." @default.
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- W1979192016 date "1986-04-01" @default.
- W1979192016 modified "2023-09-27" @default.
- W1979192016 title "Ethane hydrogenolysis catalyzed by W(100)" @default.
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- W1979192016 doi "https://doi.org/10.1016/0021-9517(86)90336-2" @default.
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