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- W1979215501 abstract "A new sensitive isothermal titration microcalorimeter using polyvinylidene difluoride (PVDF) as detector has been developed. Heat pulses of less than 0.4 μJ can be detected and the baseline noise level (p-p) is 40 nW. The calorimeter is constructed with one reaction cell (0.7 ml) insulated by several radiation shields inside a vacuum chamber. The performance of the instrument was examined by measuring the heat of protonation of Tris with HCl. The enthalpy of reaction was found to be −49±1 kJ·mol−1, in good agreement with the reported value of −47.5 kJ·mol−1." @default.
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- W1979215501 date "1994-11-01" @default.
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- W1979215501 title "A high sensitivity titration calorimeter using pyroelectric sensor" @default.
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- W1979215501 doi "https://doi.org/10.1007/bf02547110" @default.
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