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- W1979217836 abstract "Aus Bis-2.2′-biphenylylen-phosphonium-jodid (1) gewinnt man mit Arylendiolaten die hexa-koordinierten Phosphor enthaltenden onium-at-Komplexe 3 und 6. Bei der Umsetzung von Phosphorpentachlorid oder Chlorphosphoran 10 mit o-Phenylendiolat entsteht das Tris- o-phenylendioxy-phosphat-Anion (9), das ebenfalls in From stabiler oniun-at-Komplexe isoliert wurde. Die IR- und 31P-NMR-Daten der neuen Verbindungen werden diskutiert. Phosphate Complexes with o-Phenylendioxy Groups Reaction of bis(2,2′-biphenylylene)phosphonium ilodide (1) with arylendiolates leads to the formation of the onium-ate complexes 3 und 6 containing hexacoordinated phosphorus. Similarly phosphorus pentachloride or chlorophosporane 10 react with o-phenylene-diolate to yield the tris(o-phenylenedioxy)phosphate anion 9, which was also isolated in the form of stable onium-ate complexes. I. r. and 31P n.m.r. data of the new compounds are discussed." @default.
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- W1979217836 date "1970-04-01" @default.
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- W1979217836 title "Phosphat‐Komplexe mit O‐Phenylendioxy‐Gruppen" @default.
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- W1979217836 doi "https://doi.org/10.1002/cber.19701030409" @default.
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