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- W1979228114 abstract "Abstract For poly(methyl methacrylate) (PMMA) containing incompatible diethyl siloxane oligomer (DES), the effect of DES on the mechanical behavior of polymer was discussed in terms of the structural plasticization. Using positron annihilation lifetime spectroscopy (PALS), the introduction of DES to polymer was shown to change the free volume content primarily within structural sublevels with lowered packing densities. Examination of polymer samples using the studies in the temperature-induced recovery of residual deformation, dynamic mechanical analysis, differential scanning calorimetry, and thermostimulated luminescence evidenced that the changes in the polymer microstructure control the variations in the molecular and segmental mobility in PMMA. Enhancement of the molecular and segmental mobility decreases the mechanical parameters such as elastic modulus and yield stress whereas the restriction of molecular and segmental mobility increases the above mechanical characteristics. Mechanism of structural..." @default.
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- W1979228114 date "2000-09-01" @default.
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- W1979228114 title "Physical and Mechanical Behavior of Polymer Glasses. V. Structural Plasticization" @default.
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- W1979228114 doi "https://doi.org/10.1080/00914030008035058" @default.
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