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- W1979287238 abstract "The transformation of ketochlorohydrins into the corresponding ketoepoxides by the usual method, employing methanolic potassium hydroxide, gave significant amounts of methoxy alcohol along with the ketoepoxide. However, treatment of ketochlorohydrin with dilute potassium hydroxide in a chloroform-water system in the presence of cetyltrimethylammonium bromide (CTAB) smoothly furnished the ketoepoxide in excellent yield with no undesired methoxy alcohol. This phase-transfer catalysis method was thus advantageous in terms of speed, selectivity and simplicity. Catalytic activity of the cationic surfactant, CTAB, was higher than that of anionic or nonionic surfactants." @default.
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- W1979287238 date "1990-12-01" @default.
- W1979287238 modified "2023-09-24" @default.
- W1979287238 title "Phase-transfer catalysed transformation of chlorohydrins to epoxides" @default.
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- W1979287238 doi "https://doi.org/10.1016/0304-5102(90)85136-6" @default.
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