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• W1979289620 endingPage "222" @default.
• W1979289620 startingPage "219" @default.
• W1979289620 abstract "Phosphide anions, prepared by an action of sodium dihydridobis(2-methoxyethanolato)aluminate on derivatives of phosphine, phosphine oxide, or phosphorus esters, react with primary and secondary alkyl halides to produce phosphine derivatives having a newly formed phosphorus-carbon bond. The reactivity increases in the order of chloride<bromide<iodide and of secondary<primary in alkyl halide. Reaction of phosphide anion is also feasible with p-toluenesulfonate. Reaction of an anion of diphenylphosphine oxide seems to proceed mainly as an SN2 type process." @default.
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• W1979289620 date "1983-01-01" @default.
• W1979289620 modified "2023-10-16" @default.
• W1979289620 title "Nucleophilic Substitution with Phosphide Anions Prepared by an Action of Sodium Dihydridobis(2-methoxyethanolato)aluminate on Phosphorus Compounds" @default.
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• W1979289620 doi "https://doi.org/10.1246/bcsj.56.219" @default.
• W1979289620 hasPublicationYear "1983" @default.
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