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• W1979322458 abstract "A new idea for hydrogen storage is proposed in which H+ ions are adsorbed chemically on graphene sheet and it is possible to overcome the fundamental problem of current methods that hydrogen is not able to reversibly adsorbed/desorbed in appropriate temperature and under moderate pressure. As the top priority to test the feasibility, H+ ions storing capacity is studied by theoretical calculations. And the bonding and structural properties of H+/graphene complexes are investigated thoroughly. Our data yield promising results. The graphene fragment C62H20, in a quasi one-dimensional arch-like tunnel geometry, can absorb up to 54 H+ ions on the same side (6.6 wt.% H2) while maintaining its conductivity because of the sp2-rich structure. The feasibility of the new idea is proved from a viewpoint of hydrogen storing capacity. Additional calculation using an infinite graphene sheet model gives credibility to our conclusions. Considering the successful development of synthesis techniques in mass-producing atom-thick graphene sheets, it is really worth expecting a hydrogen-based energy economy can be realized by hydrogen-ion storage graphene electrodes." @default.
• W1979322458 created "2016-06-24" @default.
• W1979322458 creator A5053773525 @default.
• W1979322458 date "2011-10-01" @default.
• W1979322458 modified "2023-10-16" @default.
• W1979322458 title "H+ ions on graphene electrode as hydrogen storage reservoirs" @default.
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• W1979322458 doi "https://doi.org/10.1016/j.commatsci.2011.06.012" @default.
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