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Matches in SemOpenAlex for { <https://semopenalex.org/work/W1979340928> ?p ?o ?g. }

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• W1979340928 abstract "A simple and efficient synthetic route to the bicyclic α,β-unsaturated β-keto ester methyl (3aS,7aS)-6-oxo-2,3,3a,6,7,7a-hexahydro-1H-indene-5-carboxylate, a versatile intermediate in the synthesis of biologically active unsaturated 1,4-dialdehydes, is described. The synthesis includes a chirality introducing nonenzymatic asymmetric desymmetrization (ADS) reaction of a cyclic meso-anhydride 4 and a modified Hofmann method for preparing exocyclic dienes. The ester was synthesized in a moderate overall yield (19%) from 6 and with an excellent enantioselectivity (>90%)." @default.
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• W1979340928 date "2007-01-01" @default.
• W1979340928 modified "2023-10-14" @default.
• W1979340928 title "Enantioselective formal synthesis of tridemethylisovelleral" @default.
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• W1979340928 doi "https://doi.org/10.1016/j.tetlet.2006.11.122" @default.
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