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• W1979389306 abstract "We report extensive, fully quantum, time-independent (TID) calculations of cross sections at low collision energies and rate constants at low temperatures for the O+OH reaction, of key importance in the production of molecular oxygen in cold, dark, interstellar clouds and in the chemistry of the Earth’s atmosphere. Our calculations are compared with TID calculations within the J-shifting approximation, with wave-packet calculations, and with quasiclassical trajectory calculations. The fully quantum TID calculations yield rate constants higher than those from the more approximate methods and are qualitatively consistent with a low-temperature extrapolation of earlier experimental values but not with the most recent experiments at the lowest temperatures." @default.
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• W1979389306 date "2009-12-14" @default.
• W1979389306 modified "2023-09-27" @default.
• W1979389306 title "O+OH→O2+H: A key reaction for interstellar chemistry. New theoretical results and comparison with experiment" @default.
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• W1979389306 doi "https://doi.org/10.1063/1.3274226" @default.
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