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- W1979402308 abstract "Abstract The preparation is described of the compounds ML2X2 (L = 2,6-dimethyl-4-thiopyrone: M = Co, Ni or Zn, X = Cl, Br or I) and CuL2Cl. From optical spectra, magnetic moments and X-ray powder patterns electronic and structural information is deduced. The cobalt and zinc compounds, CoL2X2 and ZnL2X2, have pseudo-tetrahedral structure, and NiL2X2 are highly distorted tetrahedra. The B′ values for CoL2X2 are fairly low compared to those for the 2,6-dimethyl-4-pyrone-cobalt complexes. For zinc complexes, coordination through sulphur atom is confirmed, and tentative assignments are made for the metal-sulphur stretching frequency." @default.
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- W1979402308 date "1975-10-01" @default.
- W1979402308 modified "2023-09-24" @default.
- W1979402308 title "Complexes of 2,6-dimethyl-4-thiopyrone with Co(II), Ni(II), Zn(II) and Cu(I)" @default.
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- W1979402308 doi "https://doi.org/10.1016/0022-1902(75)80829-3" @default.
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