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• W1979410634 abstract "Abstract The two novel thioantimonates(III) (C 6 N 3 H 17 2+ )Sb 6 S 10 ( I ) and (C 7 N 2 H 13 + ) 3 Sb 9 S 15 ( II ) were synthesized under solvothermal conditions reacting Sb and S with the amines 1‐(2‐aminoethyl)‐piperazine (C 6 N 3 H 15 ) and 1, 5‐diazabicyclo[4.3.0.]non‐5‐en (DBN, C 7 N 2 H 12 ), respectively. The compounds crystallize as red needles in the monoclinic non‐centrosymmetric space group P2 1 ( I ) and in the monoclinic space group P2 1 /c ( II ) with lattice parameters a = 6.120(4) Å, b = 17.759(1) Å, c = 11.478(7) Å, β = 90.70(7)° for I and a = 10.2643(6) Å, b = 23.648(2) Å, c = 20.4655(11) Å, β = 104.430(7)° for II . In both compounds the primary building units (PBUs) are trigonal SbS 3 pyramids and SbS 4 moieties. The interconnection of these PBUs leads to the formation of six‐membered rings Sb 3 S 3 and Sb 3 S 4 semi‐cubes in I which are joined via common S atoms to form the one‐dimensional [Sb 6 S 10 ] 2‐ anion being directed along [001]. Neighbored chains are arranged in a way that pockets are formed which host the organic cations. The ammonium groups of the organic molecules are oriented towards the anion ensuring optimal S···H bonding interactions. Taking into account the longer Sb‐S bonds above 3Å a three‐dimensional network is formed with large cages containing the organic cations. In compound II the SbS 3 pyramids and the SbS 4 units each form individual chains by vertex linking. The central chain is exclusively formed by SbS 4 units whereas the other two chains are composed of SbS 3 pyramids. The interconnection of the chains via common corners yields the one‐dimensional [Sb 9 S 15 ] 3‐ multiple chain anion. Due to the connection mode Sb 4 S 4 rings are formed which are condensed along [001]. The chains are stacked along [100] with an inter‐chain separation of about 7Å. In the [010] direction the anions are lined‐up with the shortest distance between neighbored anions of about 3.4Å. With the long Sb‐S distances layers within the (100) plane are formed. At elevated temperatures both compounds decompose via an internal redox reaction into Sb 2 S 3 (Stibnite) and Sb. The optical band gaps of about 2 eV indicate that both compounds are semiconductors." @default.
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• W1979410634 date "2004-10-26" @default.
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• W1979410634 title "Two Novel Thioantimonates(III) with the Same Stoichiometric Sb:S Ratio but Different Crystal Structures: Solvothermal Synthesis, Crystal Structures, Thermal Stability and Spectroscopy of (C₆N₃H₁₇)Sb₆S₁₀ and (C₇N₂H₁₃)₃Sb₉S₁₅" @default.
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• W1979410634 doi "https://doi.org/10.1002/zaac.200400194" @default.
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