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• W1979433336 abstract "Abstract A facile approach, based on the polyelectrolyte‐mediated electrostatic adsorption of a water‐soluble titanium complex on colloid templates and hydrothermal treatment, is presented for the formation of hollow TiO 2 spheres of the desired polymorphs. The core–shell particles were formed by the alternate deposition of titanium–glycolate complex 1 and positively charged polyelectrolyte, poly(allylamine hydrochloride) (PAH) on spherical polystyrene (PS) templates by utilizing electrostatic interactions for shell formation. Hollow spheres formed with the polyionic complex of 1 and PAH were obtained by removal of the PS templates. Formation of the polyionic complex affected the crystallization of TiO 2 from 1 by hydrothermal treatment. Hollow spheres of brookite and anatase were obtained by hydrothermal treatment at pH 4 and 10, respectively. The approach presented here can be exploited for the fabrication of novel advanced titania‐based materials with desired structures and polymorphs." @default.
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• W1979433336 date "2012-06-06" @default.
• W1979433336 modified "2023-10-16" @default.
• W1979433336 title "Preparation of Hollow TiO ₂ Spheres of the Desired Polymorphs by Layer‐by‐Layer Assembly of a Water‐Soluble Titanium Complex and Hydrothermal Treatment" @default.
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• W1979433336 doi "https://doi.org/10.1002/ejic.201200421" @default.
• W1979433336 hasPublicationYear "2012" @default.
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