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- W1979442857 abstract "A study of the infrared absorption spectrum of the azide ion in a KBr lattice shows that its thermal decomposition results in the formation of the cyanate ion, NCO−. From investigations of the various isotopically substituted species it was found that azide decomposes by reaction with trapped carbon dioxide, an impurity which is generally present under the conditions of the pressed-disc technique. Furthermore, only a single end-nitrogen atom of each azide ion participates in cyanate formation. The frequencies of the fundamental modes of the azide ion in TlBr, TlCl and AgCl matrices are reported and compared with those of N3− in other lattices." @default.
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- W1979442857 date "1967-06-01" @default.
- W1979442857 modified "2023-09-25" @default.
- W1979442857 title "Infrared study of thermal decomposition of the azide ion" @default.
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- W1979442857 doi "https://doi.org/10.1016/0584-8539(67)80076-x" @default.
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