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- W1979459580 abstract "Mössbauer measurements have been carried out on neat solid samples of diphenyltin(IV) dichloride at liquid nitrogen temperature, as well as on frozen solution samples of this solute in crystalline and glassy matrices. The isomer shift and quadrupole splitting observed for the neat solid-1·359 ± 0·015 and 2·812 ± 0·015 mm/sec, respectively — reflect in part the effect of crystal stacking forces which influence the metal-ligand bond angles and hence the Mössbauer parameters. The quadrupole splitting decreases by about 0·20 mm/sec in non-basic solvents and a value of 2·61 ± 0·04 mm/sec for this parameter is taken as characteristic of an isolated unrestrained molecule of the solute. The increase to 3·51 ± 0·09 mm/sec in basic solvents reflects the coordination of two solvent molecules, giving rise to a distorted trans octahedral complex in which the two aryl groups occupy axial positions. The temperature dependence of the recoil-free fraction in neat solid >2SnCl2 has been determined in the temperature range 83 < T < 170°K and can be used to estimate the importance of intermolecular bonding forces in comparable organotin(IV) compounds by a simple normalization procedure." @default.
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- W1979459580 date "1973-01-01" @default.
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- W1979459580 title "Diphenyltin(IV)_dichloride as a model compound in Mössbauer spectroscopy" @default.
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- W1979459580 doi "https://doi.org/10.1016/0022-1902(73)80610-4" @default.
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